Sealing Glass

Mo-Sci has taken two distinct approaches to developing high-temperature sealant materials for solid oxide fuel cells (SOFCs) and other applications such as sodium-ion batteries. The first is the traditional glass-ceramic seal in which the glass crystallizes and bonds to seal components.

The second approach bonds to metals and ceramics, but the alkali-free composition of the glass has been tailored to operate in a viscous state while resisting crystallization. Compliant or viscous glass seals are a new class of SOFC seal and are designed to be vitreous at the SOFC stack operating temperatures. Viscous seals have the potential to reduce the risk that thermal stresses will result in catastrophic seal failure through viscous healing of cracks if they form during thermal cycling.

 

Note: This is an area of current research and development and additional compositions are in the commercialization process at this time. Please contact MO-SCI about the availability of other compositions if the options above will not suit your application.

 


Mo-Sci Sealing Glass Selector

wdt_ID Glass Glass Seal Type Applicable Materials Max Operational Temp (°C) Min Firing Temp (°C) Max Firing Temp (°C) CTE Crystalized (ppm/°C) CTE As Cast (ppm/°C) Tc (°C) Td (°C) Tg (°C) Density (g/cm3) Resistant to Alkali Color
1 GL1701 glass-ceramic Alumina, Aluminum Nitride, Mullite, Sapphire, Steatite, Yttria 1,600 1,200 6.00 1,000 1,200 750 2.60 No white
2 GL1702 glass-ceramic Alumina, Yttria, Sapphire, Steatite 1,200 900 1,200 8.00 7.90 880 697 670 3.50 No white
3 GL1862 glass-ceramic Alloy 52, Ferrite, Forsterite, Stainless Steel 4XX, Titanium, YSZ, Zirconia 1,000 850 925 10.30 10.00 1,028 762 725 3.40 No white
4 GL1873 glass-ceramic Alumina, Yttria, Sapphire, Steatite 1,000 800 820 7.60 8.30 827 700 651 2.60 No white
5 GL1850 glass-ceramic Aluminum Nitride, Mullite, Silicon Carbide, Silicon Nitride, Tungsten 970 1,250 1,250 3.50 3.90 1,250 849 815 2.40 No white
6 GL1870 glass-ceramic Alumina, Yttria, Sapphire, Steatite 910 1,020 1,020 9.10 9.60 1,037 754 724 3.20 No white
7 GL1883 glass Aluminum Nitride, Mullite, Silicon Carbide, Silicon Nitride, Tungsten 900 950 970 3.50 599 462 2.10 No white
8 GL1810 glass-ceramic Inconel Alloys, Stainless Steel 3XX, Copper 900 820 1,000 16.00 10.00 815 682 575 2.40 No white
9 GL1729 glass-ceramic Alloy 52, Ferrite, Forsterite, Stainless Steel 4XX, Titanium, YSZ, Zirconia 900 790 890 11.00 10.90 890 750 690 3.50 No white
10 GL1497 glass-ceramic Alloy 52, Ferrite, Forsterite, Stainless Steel 4XX, Titanium, YSZ, Zirconia 900 760 830 10.00 9.60 830 718 640 3.30 No brown
Glass Seal Type Applicable Materials Max Operational Temp (°C) Min Firing Temp (°C) Max Firing Temp (°C) CTE Crystalized (ppm/°C) CTE As Cast (ppm/°C) Tc (°C) Td (°C) Tg (°C) Resistant to Alkali